Journal
RSC ADVANCES
Volume 4, Issue 42, Pages 22035-22041Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c4ra02846e
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Funding
- International Center for Young Scientists (ICYS) on Materials Nanoarchitectonics (WPI-MANA)
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Through appropriate engineering of the 5,5'-bis(mercaptomethyl)-2,2'-bipyridine self-assembled monolayer (BPD-SAM) on a gold surface, ultrathin sulfur functionalized freestanding carbon-metal nanosheets (CMNS) have been produced. The BPD-SAM was used to encapsulate Ni+2. The resulting BPD-Ni+2 SAM was cross-linked by high-energy electrons. The nanomembrane was realized by dissolving the gold substrate. The chemical and physical properties of the CMNS were investigated using X-ray photoelectron spectroscopy (XPS), UV-vis reflection spectroscopy, atomic force microscopy (AFM), scanning electron microscopy (SEM), energy dispersive X-ray (EDX), and electrical two-point probe measurements.
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