Journal
RSC ADVANCES
Volume 4, Issue 93, Pages 51105-51110Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c4ra08477b
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Funding
- National Science Foundation (NSF) through the Renewable Energy Materials Research Science and Engineering Center [DMR-0820518]
- Colorado School of Mines
- NSF [CMMI-1200547, CHE-1013029]
- Directorate For Engineering [1200547] Funding Source: National Science Foundation
- Division Of Chemistry
- Direct For Mathematical & Physical Scien [1013029] Funding Source: National Science Foundation
- Div Of Civil, Mechanical, & Manufact Inn [1200547] Funding Source: National Science Foundation
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We report a mild, effective, room-temperature method for brominating and functionalizing colloidal hydrogen-terminated silicon quantum dots (H-SiQDs) using N-bromosuccinimide (NBS) as the bromination reagent. This post-synthesis bromination overcomes a long-standing challenge of producing emissive SiQDs through the functionalization of directly synthesized halogen-terminated colloidal SiQDs.
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