Journal
RSC ADVANCES
Volume 4, Issue 34, Pages 17429-17433Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c4ra00894d
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Core-shell poly(dimethylsiloxane) (PDMS)-MOF 5 microspheres were prepared by directed crystallization of MOF 5 on thermally stable PDMS beads. The microspheres were evaluated for their potential use as a stationary phase for gas-chromatographic separation of permanent gases and liquids, where the issues associated with pressure drop were circumvented. The successful demonstration of this simple and versatile methodology widens the scope for large-scale application of Metal-Organic Frameworks (MOFs) in chromatographic separation.
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