4.6 Article

Facile synthesis of NiMoO4 center dot xH(2)O nanorods as a positive electrode material for supercapacitors

Journal

RSC ADVANCES
Volume 3, Issue 18, Pages 6472-6478

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c3ra22993a

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Funding

  1. National Natural Science Foundation of China [21163010]
  2. Key Project of the Chinese Ministry of Education [212183]
  3. Natural Science Funds for Distinguished Young Scholars of Gansu Province [1111RJDA012]

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NiMoO4 center dot xH(2)O nanorods with one-dimensional structures and high performances are synthesized by a facile chemical co-precipitation method. A maximum specific capacitance of 1136 F g(-1) is achieved at a current density of 5 mA cm(-2). The fabricated NiMoO4 center dot xH(2)O is a good positive electrode material for supercapacitors due to its unique structure and excellent capacitive properties. To enhance the energy density and enlarge the potential window, an asymmetric supercapacitor is assembled using NiMoO4 center dot xH(2)O as the positive electrode and activated carbon (AC) as the negative electrode in 2 M aqueous KOH electrolyte. It exhibits a high energy density and stable power characteristics. A maximum specific capacitance of 96.7 F g(-1) and specific energy of 34.4 W h kg(-1) are demonstrated for a cell voltage between 0 and 1.6 V, indicating that the fabrication of an asymmetric supercapacitor is an effective way to enhance the energy density.

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