Journal
RSC ADVANCES
Volume 3, Issue 33, Pages 13702-13704Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c3ra42834f
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Funding
- MEXT
- JSPS
- Grants-in-Aid for Scientific Research [21106003, 24550122] Funding Source: KAKEN
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The a-alkylation reaction of acetamides with primary alcohols to afford the corresponding amides was accomplished effectively using RuHCl(CO)(PPh3)(3) as a catalyst, nitrogen tridentate ligand L1 as an additive, and (KOBu)-Bu-t as a base. While the addition of bpy was effective only for benzylic alcohols, L1 affected the alkylation reaction when both benzylic and non-benzylic type alcohols were used.
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