4.6 Article

Mesoporous iron oxide directly anchored on a graphene matrix for lithium-ion battery anodes with enhanced strain accommodation

Journal

RSC ADVANCES
Volume 3, Issue 3, Pages 699-703

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c2ra22702a

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Funding

  1. National Natural Science Foundation of China [51202106, 61076017, 60928009]
  2. Fundamental Research Funds for the Central Universities [1127021010]
  3. 973 Project [2013CB932900]

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A continuous mesoporous iron oxide nanofilm was directly formed on graphene nanosheets through the in situ thermal decomposition of Fe(NO3)(3)center dot 9H(2)O and was anchored tightly on the graphene surface. The lithiation-induced strain was naturally accommodated, owing to the constraint effect of graphene and the mesoporous structure. Hence, the pulverization of the iron oxide nanofilm was effectively prevented.

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