4.6 Article

Cu-Ni@ SiO2 alloy nanocomposites for methane dry reforming catalysis

Journal

RSC ADVANCES
Volume 3, Issue 46, Pages 23976-23979

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c3ra43203c

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Funding

  1. National Natural Science Foundation of China [51172142]
  2. Starting Foundation for New Teacher of Shanghai Jiao Tong University [12X100040119]
  3. Shanghai Municipal Natural Science Foundation [12ZR1414300]
  4. Third Phase of 211 Project for Advanced Materials Science [WS3116205006, WS3116205007]

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Cu-Ni alloy nanoparticles (12 +/- 3 nm) encapsulated in a silica shell have been successfully synthesized through amicroemulsion method followed by polymerization of TEOS. The morphologies of the CuNi@ SiO2 nanocomposites can be controlled by tuning the metal ion concentrations. The alloy nanostructure shows a superior performance in catalytic methane dry reforming to the pure Ni nanocomposite catalyst.

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