4.6 Article

Ni(salphen)-based metal-organic framework for the synthesis of cyclic carbonates by cycloaddition of CO2 to epoxides

Journal

RSC ADVANCES
Volume 3, Issue 7, Pages 2167-2170

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c2ra22550f

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Funding

  1. National Natural Science Foundation of China [20932002, 21172076]
  2. National Basic Research Program of China (973 Program) [2011CB808600]
  3. Natural Science Foundation of Guangdong Province, China [10351064101000000]
  4. Fundamental Research Funds for the Central Universities [2011ZM0044]

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A well-defined homogeneous molecular catalyst Ni(salphen) was introduced as a metalloligand in a MOF, providing an efficient and recyclable heterogeneous catalyst for the synthesis of cyclic carbonates by the cycloaddition of CO2 to epoxides under relatively mild conditions.

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