Journal
RSC ADVANCES
Volume 3, Issue 45, Pages 23508-23513Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c3ra43451f
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Funding
- Ministry of Education, Culture, Sports, Science and Technology, Japan [24550165]
- Takahashi Industrial and Economic Foundation
- Grants-in-Aid for Scientific Research [24550165] Funding Source: KAKEN
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The chiroptical properties of two viscous chiral fluorophores, (R)-2,2'-hepthoxy-1,1'- binaphthyl [(R)-1] and its antipode [(S)- 1], dispersed in inorganic (KBr and KCl) and organic polymer ( PMMA and PS) matrices are studied in the photoexcited and ground states. Both (R)-1 and (S)-1 emit circularly polarised luminescence (CPL) with a high quantum efficiency in these solid matrices (15-58%) and in chloroform solution (14%).
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