4.6 Article

Non-stoichiometry in CaCu3Ti4O12 (CCTO) ceramics

Journal

RSC ADVANCES
Volume 3, Issue 34, Pages 14580-14589

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c3ra41319e

Keywords

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Funding

  1. European Union [226716]
  2. EPSRC (UK) [EP/G005001/11]
  3. MINECO (Spain)
  4. EPSRC [EP/G005001/1, EP/E040578/1] Funding Source: UKRI
  5. Engineering and Physical Sciences Research Council [EP/G005001/1, EP/E040578/1] Funding Source: researchfish

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A combined powder X-ray lattice parameter and ceramic impedance spectroscopy study is presented on materials within the CaO-CuO-TiO2 ternary phase diagram. Several compositions containing CaCu3Ti4O12 (CCTO) and small amounts of secondary phases such as TiO2, CaTiO3 and CuO are analysed and two different defect mechanisms are identified as the cause of the non-stoichiometry in CCTO. The first mechanism involves a variation in the Cu content, which explains the large differences in the intrinsic bulk and extrinsic grain boundary (GB) resistance, and the formation of the ceramic internal barrier layer capacitor (IBLC) structure. The second mechanism is associated with Ca-Cu anti-site disorder causing an unusually high intrinsic bulk permittivity above that predicted from Clausius-Mossotti calculations.

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