Journal
RSC ADVANCES
Volume 3, Issue 22, Pages 8276-8285Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c3ra40451j
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Funding
- U.S. Department of Energy
- FreedomCAR
- Vehicle Technologies Office
- Department of Energy (DOE) Office of Energy Efficiency and Renewable Energy (EERE) Postdoctoral Research Award under the EERE Vehicles Technology Program
- Oak Ridge Associated Universities (ORAU) under DOE [DE-AC05-06OR23100]
- DOE Office of Science-Basic Energy Sciences [DE-AC02-06CH11357]
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Uniformly dispersed core-shelled Fe/Fe3O4 nanocomposite on porous carbon was synthesized via a wet-chemistry approach, which was tested as a cathode material in rechargeable Li-O-2 battery, showing highly active catalytic effect towards the electrochemical reactions, of particular, oxygen reduction reaction. XPS data showed the oxygen reduction reaction took place on the surface of the catalyst during discharge of the cell. Both XRD and XPS data demonstrated that lithium peroxide partook in the reversible reactions in the Li-O-2 cell with a TEGDME-based electrolyte.
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