4.6 Article

A monophosphoryl copillar[5]arene: synthesis and host-guest complexation with alkanols

Journal

RSC ADVANCES
Volume 3, Issue 44, Pages 21405-21408

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c3ra43744b

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Funding

  1. National Natural Science Foundation of China [21072064, 21272079]
  2. National Basic Research Program of China [2012CB720801]

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A monophosphoryl copillar[5]arene 1 was prepared. The introduction of the phosphoryl group remarkably promoted the binding affinity of 1 with alkanols and alkanediols in comparison with 1,4-dimethoxypillar[5]arene. Thus 1 can form a stable 1 : 1 host-guest complex with alkanols in CDCl3.

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