4.6 Article

A new resonance Rayleigh scattering method for trace Pb, coupling the hydride generation reaction with nanogold formation

Journal

RSC ADVANCES
Volume 3, Issue 31, Pages 12585-12588

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c3ra42030b

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Funding

  1. National Natural Science Foundation of China [21267004, 21165005]
  2. Natural Science Foundation of Guangxi [2013GXNSFFA019003]
  3. Guangxi Key Laboratory of Environmental Pollution Control Theory and Technology

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Pb2+ was oxidized to Pb4+ and was reduced to PbH4 gas by NaBH4, and the gas was reacted with Au3+ to form nanogold that exhibited a resonance Rayleigh scattering effect at 286 nm. Based on this, 0.2 x 10(-6)-33.6 x 10(-6) mol L-1 Pb can be detected, with a detection limit of 7.0 x 10(-8) mol L-1.

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