Journal
RSC ADVANCES
Volume 3, Issue 40, Pages 18332-18338Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c3ra42309c
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- DST, New Delhi, India
- CSIR, India
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An efficient synthetic strategy is described for the construction of amino acids derived enantiomerically pure cis-2,5-disubstituted chiral piperazines. Cu-catalyzed spontaneous regioselective ring opening and ring closing of non-activated N-tosyl aziridines as well as Pd-mediated N-C bond formation from N-tosyl halogenated amino-derivatives are the key steps for accessing disubstituted piperazines.
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