4.6 Article

Sterically congested pyrrole-fused tetrathiafulvalene decamers as highly conductive amorphous molecular materials

Journal

RSC ADVANCES
Volume 2, Issue 8, Pages 3221-3224

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c2ra00035k

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Funding

  1. MEXT, Japan [23750045]
  2. Noguchi Institute
  3. Asahi Glass Foundation
  4. Grants-in-Aid for Scientific Research [22350021] Funding Source: KAKEN

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Sterically congested pyrrole-fused tetrathiafulvalene (TTF) decamer 4 was designed and synthesized via the SNAr reaction of decafluorobiphenyl with the corresponding pyrrolyl sodium salt, which formed amorphous spin-coated films showing good conductivity of up to 4.4 S cm(-1) after iodine doping as the result of multi-dimensional pi-pi stacking between the TTF units.

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