Journal
RSC ADVANCES
Volume 2, Issue 15, Pages 6164-6166Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c2ra20968c
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Funding
- MINECO [CTQ2008-00947/BQU]
- DEC [2009SGR623]
- ICIQ Foundation
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Enantiopure trans-3-trifluoromethylsulfonylamino-4-silyloxypyrrolidines efficiently catalyse the asymmetric alpha-aminoxylation of aldehydes. At 1% catalyst loading (solvent-free conditions) or at 2% catalyst loading (acetonitrile solution) aldehydes are completely converted in short reaction times leading to alpha-aminoxylation products with very high (96-99%) enantioselectivity.
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