4.6 Article

CuO nano particles and [bmim]BF4: an application towards the synthesis of chiral β-seleno amino derivatives via ring opening reaction of aziridines with diorganyl diselenides

Journal

RSC ADVANCES
Volume 2, Issue 22, Pages 8478-8482

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c2ra21488a

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Funding

  1. CNPq
  2. CAPES
  3. FAPERGS [PRONEM11/2080-9]
  4. TWAS-CNPq

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A series of chiral beta-seleno amino derivatives were synthesized via a ring opening reaction of different aziridines with diorganyl diselenides mediated by recyclable CuO nanopowder and an ionic liquid affording the corresponding products in good to excellent yields. The [bmim]BF4 ionic liquid acts as both promoter and reaction medium. Compared to the usual organic solvents the ionic liquid exhibited better performance with the advantage of its recyclability.

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