4.6 Article

Printable thin film supercapacitors utilizing single crystal cobalt hydroxide nanosheets

Journal

RSC ADVANCES
Volume 2, Issue 4, Pages 1508-1515

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c1ra01061a

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Funding

  1. National Natural Science Foundation of China [21050110115]
  2. Royal Society [JP090644]
  3. Hunan Province Foundation of Natural Science [10JJ6026]

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Cobalt hydroxide (beta-Co(OH)(2)) thin film supercapacitors are developed for the first time via screen printing and their potential application towards energy storage (as an electrode material within a supercapacitor) explored. The highly uniform, porous nanostructures were synthesized via a novel, hydrothermal, template-free approach. The nanostructures consist of amassing, arbitrarily layered, interconnecting nanosheets, resulting in a flower-like structure with many fissures. These nanostructures were fabricated into flexible thin film supercapacitors via screen printing for the first time. The beta-Co(OH)(2) asymmetric supercapacitor is found to deliver a maximum specific capacitance of similar to 170 F g(-1) at a current density of 0.5 mu A in an aqueous electrolyte solution (3M KOH) retaining 99.69% of its maximum capacity over 600 cycles. Given the ability to mass produce such supercapacitors via screen printing, where readily, synthetically fabricated nanostructures can be incorporated, the application of this approach will likely be widely implemented.

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