Journal
RSC ADVANCES
Volume 2, Issue 6, Pages 2454-2461Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c2ra01153k
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Funding
- National Institute of Health [CA67771]
- National Science Foundation [CHE-0750357]
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The synthesis of the family of new non-natural trimeric oligobenzamides (potential inhibitors of protein-protein interactions) bearing the following groups (R = isobutyl, isopropyl, CH2CONH2, (CH2)(4)NH2, benzyl) that mimic different amino acid residues (leucine, valine, asparagine, lysine, phenylalanine) was accomplished through an iterative (n + 1) elongation approach that includes reduction of the NO2-group (Pd/C, H-2) and subsequent amide coupling in the presence of Mukaiyama's reagent.
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