4.6 Article

A novel method to reduce the influence of by-product water on the catalytic performance of PdCl2/Cu-HMS catalysts for the synthesis of diethyl carbonate

Journal

RSC ADVANCES
Volume 2, Issue 11, Pages 4593-4595

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c2ra20529g

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Funding

  1. National Natural Science Foundation of China (NSFC) [21106054]
  2. Specialized Research Fund for the Doctoral Program of Higher Education (New Teachers) [20100093120003]
  3. Fundamental Research Funds for the Central Universities [JUSRP211A07]

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A novel method to synthesise diethyl carbonate is introduced by the coupling reaction, the hydrolysis of diethyl ether (DEE) and oxidative carbonylation of ethanol, which reduces the influence of by-product water and satisfies the energy coupling for the reaction system.

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