4.6 Article

Brownian dynamics determine universality of charge transport in ionic liquids

Journal

RSC ADVANCES
Volume 2, Issue 12, Pages 5047-5050

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c2ra20560b

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Funding

  1. Deutsche Forschungsgemeinschaft under the DFG [SPP 1191]
  2. Polish State of Committee for Scientific Research [N N202 023440]

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Broadband dielectric spectroscopy is employed to investigate charge transport in a variety of glass-forming ionic liquids over wide frequency, temperature and pressure ranges. Using a combination of Einstein, Einstein-Smoluchowski, and Langevin relations, the observed universal scaling of charge transport in ionic liquids is traced back to the dominant role of Brownian dynamics.

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