Journal
REACTION KINETICS AND CATALYSIS LETTERS
Volume 94, Issue 2, Pages 207-218Publisher
SPRINGER
DOI: 10.1007/s11144-008-5342-2
Keywords
clay; laser flash photolysis; hydroxyl radical; iron
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Funding
- Natural Science Foundation of P.R. China [40503016]
- NSFC-RFBR cooperation [20611120016, 05-03-39007]
- RFBR [06-03-32110]
- Siberian Branch of Russian Academy of Sciences [4.16]
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With the use of laser flash photolysis, the formation of hydroxyl radicals upon the photolysis of an iron-rich clay (montmorillonite KSF) was demonstrated. The (OH)-O-center dot radical was shown to be formed by the photolysis of the Fe(OH)(aq)(2+) complex that escaped from the clay into the solution bulk.
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