Journal
MATERIALS
Volume 7, Issue 1, Pages 611-622Publisher
MDPI
DOI: 10.3390/ma7010611
Keywords
self-assembly; metalla-cages; metal-driven; tetrathiafulvalene; redox
Categories
Funding
- CNRS
- Region des Pays de la Loire
- MENRT
- University of Angers
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Two self-assembled redox-active cages are presented. They are obtained by coordination-driven self-assembly of a tetra-pyridile tetrathiafulvalene ligand with cis-M(dppf)(OTf)(2) (M = Pd or Pt; dppf = 1,1'-bis(diphenylphosphino)ferrocene; OTf = trifluoromethane-sulfonate) complexes. Both species are fully characterized and are constituted of 12 electro-active subunits that can be reversibly oxidized.
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