4.6 Article

Effect of Annealing Temperature on the Mechanical and Corrosion Behavior of a Newly Developed Novel Lean Duplex Stainless Steel

Journal

MATERIALS
Volume 7, Issue 9, Pages 6604-6619

Publisher

MDPI AG
DOI: 10.3390/ma7096604

Keywords

lean duplex stainless steel; annealing temperature; mechanical properties; TRIP effect; pitting corrosion behavior; PREN; Volta potential

Funding

  1. National Natural Science Fund of China [51371053, 51131008, 51134010]
  2. National Key Technology RD Program [2012BAE04B00]
  3. Discipline Development Fund of Science and Technology on Surface Physics and Chemistry Laboratory [ZDXKFZ201213]

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The effect of annealing temperature (1000-1150 degrees C) on the microstructure evolution, mechanical properties, and pitting corrosion behavior of a newly developed novel lean duplex stainless steel with 20.53Cr-3.45Mn-2.08Ni-0.17N-0.31Mo was studied by means of optical metallographic microscopy (OMM), scanning electron microscopy (SEM), magnetic force microscopy (MFM), scanning Kelvin probe force microscopy (SKPFM), energy dispersive X-ray spectroscopy (EDS), uniaxial tensile tests (UTT), and potentiostatic critical pitting temperature (CPT). The results showed that tensile and yield strength, as well as the pitting corrosion resistance, could be degraded with annealing temperature increasing from 1000 up to 1150 degrees C. Meanwhile, the elongation at break reached the maximum of 52.7% after annealing at 1050 degrees C due to the effect of martensite transformation induced plasticity (TRIP). The localized pitting attack preferentially occurred at ferrite phase, indicating that the ferrite phase had inferior pitting corrosion resistance as compared to the austenite phase. With increasing annealing temperature, the pitting resistance equivalent number (PREN) of ferrite phase dropped, while that of the austenite phase rose. Additionally, it was found that ferrite possessed a lower Volta potential than austenite phase. Moreover, the Volta potential difference between ferrite and austenite increased with the annealing temperature, which was well consistent with the difference of PREN.

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