Journal
MATERIALS
Volume 3, Issue 11, Pages 4892-4914Publisher
MDPI
DOI: 10.3390/ma3114892
Keywords
transparent conducting oxides; work function; doping; band alignment; solar cells
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Funding
- German Bundesministerium fur Bildung und Forschung (BMBF) [01SF0034]
- German Science Foundation (DFG) [SFB 595, D3, KL1225/4]
- National Science Foundation (NSF) [DMR-0602521]
- U.S. Department of Energy, Office of Basic Energy Sciences as part of an Energy Frontier Research Center (DOE) [DE-SC0001059]
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Doping limits, band gaps, work functions and energy band alignments of undoped and donor-doped transparent conducting oxides ZnO, In2O3, and SnO2 as accessed by X-ray and ultraviolet photoelectron spectroscopy (XPS/UPS) are summarized and compared. The presented collection provides an extensive data set of technologically relevant electronic properties of photovoltaic transparent electrode materials and illustrates how these relate to the underlying defect chemistry, the dependence of surface dipoles on crystallographic orientation and/or surface termination, and Fermi level pinning.
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