Journal
MATERIALS
Volume 3, Issue 8, Pages 4252-4276Publisher
MDPI AG
DOI: 10.3390/ma3084252
Keywords
scanning tunneling microscopy (STM); dynamics; adsorption-induced; self-crystallization; self-assembly
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Since the invention of scanning tunneling microscopy (STM), 2D supramolecular architectures have been observed under various experimental conditions. The construction of these architectures arises from the balance between interactions at the medium-solid interface. This review summarizes molecular motion observed in 2D-supramolecular structures on surfaces using nanospace resolution STM. The observation of molecular motion on surfaces provides a visual understanding of intermolecular interactions, which are the major driving force behind supramolecular arrangement.
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