Journal
MATERIALS
Volume 3, Issue 10, Pages 4773-4783Publisher
MDPI
DOI: 10.3390/ma3104773
Keywords
addition reaction; charge-transfer band; conjugated polymer; electrochemistry; postfunctionalization
Categories
Funding
- MEXT, Japan
- Murata Science Foundation
- Izumi Science and Technology Foundation
- Yazaki Memorial Foundation for Science and Technology
- Kato Foundation for Promotion of Science
- Association for the Progress of New Chemistry
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The postfunctionalization of the main chain alkyne moieties of carbazole containing poly(arylenebutadiynylene)s was attempted by using a high yielding addition reaction between electron rich alkynes and a strong acceptor molecule, tetracyanoethylene (TCNE). After successful postfunctionalization, the polymer band gap decreased due to the intramolecular donor-acceptor interactions. The resulting donor-acceptor alternating polymer showed a very broad charge-transfer band in the visible region as well as redox activities in both anodic and cathodic directions. The optical band gap showed good agreement with the electrochemical band gap. Furthermore, the thermal stability was enhanced after postfunctionalization. These features of the donor-acceptor alternating polymer are expected to be useful for high performance activities in organic solar cell applications.
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