Journal
NANOSCALE RESEARCH LETTERS
Volume 10, Issue -, Pages -Publisher
SPRINGEROPEN
DOI: 10.1186/s11671-015-1059-0
Keywords
Nanocomposite; Oxides; Crystallites; Morphology; Sensing performance
Funding
- Ministry of Science and Technology of Taiwan [NSC 102-2221-E-019-006-MY3]
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We successfully prepared one-dimensional ZnO-ZnFe2O4 (ZFO) heterostructures for acetone gas-sensing and photoelectrochemical applications, by using sputter deposition of ZFO crystallites on ZnO nanostructure templates. The nanoscale ZFO crystallites were homogeneously coated on the surfaces of the ZnO nanostructures. Electron microscope images revealed that the ZnO-ZFO heterostructures exhibited a serrated surface morphology. Coating the ZnO nanostructures with a ZFO aggregated layer appreciably enhanced their acetone gas-sensing capability at 250 degrees C in comparison with pure ZnO nanostructures. The presence of many depleted nanoscale ZFO crystallites, the rugged surface of the heterostructures, and electron depletion at the ZnO/ZFO interface might contribute to the enhanced acetone gas-sensing response. Furthermore, the larger surface area and higher light absorption of ZnO-ZFO relative to the surface area and light absorption of ZnO were correlated with a substantial enhancement of the photocurrent value of ZnO-ZFO in photoelectrochemical tests produced by the simulated solar light irradiation.
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