Journal
NANO ENERGY
Volume 11, Issue -, Pages 500-509Publisher
ELSEVIER SCIENCE BV
DOI: 10.1016/j.nanoen.2014.11.006
Keywords
Three-dimensional nano-network; Carbon; Li-ion battery; Anode
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Funding
- DARPA Center on Nanoscale Science and Technology for Integrated Micro/Nano-Electro-mechanical Transducers (iMINT) - Defense Advanced Research Projects Agency (DARPA) N/MEMS S&T Fundamentals program [N66001-10-1-4007]
- NNIN
- National Science Foundation [ECS-0335765]
- U.S. Department of Energy's National Nuclear Security Administration [DE-AC04-94AL85000]
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Three-dimensional (3D) network structure has been envisioned as a superior architecture for lithium ion battery (LIB) electrodes, which enhances both ion and electron transport to significantly improve battery performance. Herein, a 3D carbon nano-network is fabricated through chemical vapor deposition of carbon on a scalably manufactured 3D porous anodic alumina (PAA) template. As a demonstration on the applicability of 3D carbon nano-network for LIB electrodes, the low conductivity active material, TiO2, is then uniformly coated on the 3D carbon nano-network using atomic layer deposition. High power performance is demonstrated in the 3D C/TiO2 electrodes, where the parallel tubes and gaps in the 3D carbon nano-network facilitates fast Li ion transport. A large areal capacity of similar to 0.37 mAh cm(-2) is achieved due to the large TiO2 mass loading in the 60 pm-thick 3D C/TiO2 electrodes. At a test rate of C/5, the 3D C/TiO2 electrode with 18 nm-thick TiO2 delivers a high gravimetric capacity of similar to 240 mAh g(-1), calculated with the mass of the whole electrode. A long cycle life of over 1000 cycles with a capacity retention of 91% is demonstrated at 1C. The effects of the electrical conductivity of carbon nano-network, ion diffusion, and the electrolyte permeability on the rate performance of these 3D C/TiO2 electrodes are systematically studied. (C) 2014 Elsevier Ltd. All rights reserved.
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