Journal
GREEN CHEMISTRY LETTERS AND REVIEWS
Volume 4, Issue 1, Pages 55-61Publisher
TAYLOR & FRANCIS LTD
DOI: 10.1080/17518253.2010.500623
Keywords
ruthenium; alkynes; cyclotrimerization; microwave chemistry; water
Funding
- Spanish MICINN [CTQ2006-08485/BQU, CTQ2009-08746/BQU, CSD2007-00006]
- Gobierno del Principado de Asturias (FICYT) [IB08-036]
- MICINN
- European Social Fund
- Ramon y Cajal contract
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The ability of the bis(allyl)-ruthenium(IV) complex [{RuCl(mu-Cl)(eta(3) : eta(3) -C10H16)}(2)] (C10H16 = 2,7-dimethylocta-2, 6-diene-1,8-diyl) to promote intermolecular [2+2+2] alkyne cyclotrimerization reactions in aqueous media under microwave (MW) irradiation has been evaluated. Advantages and disadvantages of using MW vs. conventional thermal heating are discussed.
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