Journal
CATALYSIS SCIENCE & TECHNOLOGY
Volume 8, Issue 20, Pages -Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c8cy01590b
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Funding
- National Key R&D Program of China [2016YFA0202900]
- National Natural Science Foundation of China [21676239, 21622606]
- Zhejiang Provincial Natural Science Foundation of China [LR18B060001]
- Fundamental Research Funds for the Central Universities
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An improved deposition method was employed to prepare a Pd/CeO2 catalyst, which exhibited highly efficient activity in low-temperature CO oxidation (LTO). By controlling the preparation conditions, a series of different morphologies and Pd species could be obtained to clarify the structure-activity relationship in the reaction. BET, XRD, STEM, HRTEM, XPS, Raman spectra, H-2-TPR, CO/O-2 transient pulse experiments and in situ DRIFTS were used to characterize the catalysts. It was found that Pd2+ was incorporated in CeOx vacancies, while calcination facilitated the intimate mixing of Pd, O and Ce. HRTEM and STEM results showed that a special flattened Pd-Ce binary oxide cluster was achieved and evenly anchored on the CeO2 surface, then CO adsorption and oxygen oxidation occured simultaneously on the cluster, leading to extremely high activity.
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