Journal
CATALYSIS SCIENCE & TECHNOLOGY
Volume 4, Issue 1, Pages 30-33Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c3cy00644a
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- Institute for Advanced Studies in Basic Sciences
- National Elite Foundation
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In this paper a dinuclear Fe complex, [tpa(H2O)FeOFe(H2O)tpa](ClO4)(4) (tpa: tris(2-pyridylmethyl)amine) is reported as an efficient catalyst for water oxidation in the presence of cerium(IV) ammonium nitrate. The turnover frequency of this dimer is 6 times greater than the turnover frequency reported for the [Fe(OTf or Cl)(2)(tpa)] complex (OTf: trifluoromethanesulfonate). The role of FeO42- ions in the water oxidation reaction is also discussed.
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