Journal
CATALYSIS SCIENCE & TECHNOLOGY
Volume 4, Issue 6, Pages 1720-1725Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c4cy00219a
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Funding
- Department of Employment and Learning in Northern Ireland
- Engineering and Physical Sciences Research Council [1353220] Funding Source: researchfish
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A Cu(I)/9-azabicyclo[3.3.1]nonan-3-one N-oxyl (ketoABNO) aerobic catalyst system is highly effective for the oxidation of secondary alcohols, including unactivated aliphatic substrates. The effects of pressure and gas composition on catalyst performance are examined. The radical can be employed at low loadings and is also amenable to immobilisation on to solid supports.
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