Journal
CATALYSIS SCIENCE & TECHNOLOGY
Volume 4, Issue 12, Pages 4188-4192Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c4cy01018c
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Funding
- Deutsche Forschungsgemeinschaft [SFB 840, KE 756/23-1]
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Pyrroles are important compounds with several applications in medicine and material science. They can be synthesized sustainably from secondary alcohols and amino alcohols. Hydrogen and water are liberated in the course of this reaction. Here, we present that this sustainable catalytic pyrrole synthesis can be mediated efficiently by a novel iridium nanoparticle catalyst. The catalyst synthesis starts from molecular precursors, an N-ligand stabilized Ir complex and a commercially available polysilazane. The generation of nanometer-sized iridium particles was achieved (due to the presence of N atoms in the support). The robust nature of the support allows reuse of the catalyst. The scope of the reaction was verified by the synthesis of 23 pyrrole derivatives (up to 93% isolated yield). Thus, an attractive functional group tolerance (e.g. amines and olefins) could be observed. Commercially available heterogeneous Ir catalysts are inefficient in this pyrrole synthesis and extremely limited in terms of reusability.
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