4.6 Article

Homogeneous and heterogenised new gold C-scorpionate complexes as catalysts for cyclohexane oxidation

Journal

CATALYSIS SCIENCE & TECHNOLOGY
Volume 3, Issue 11, Pages 3056-3069

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c3cy00552f

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Funding

  1. Fundacao para a Ciencia e a Tecnologia (FCT)
  2. FEDER [PEst-C/EQB/LA0020/2011, PEst-OE/QUI/UI0100/2013, PTDC/EQU-EQU/122025/2010, PTDC/QUI-QUI/102150/2008, PTDC/QUI-QUI/100682/2008]

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Gold(III) complexes of type [AuCl2{eta(2)-RC(R'pz)(3)}]Cl [R = R' = H (1), R = CH2OH, R' = H (2) and R = H, R' = 3,5-Me-2(3), pz = pyrazol-1-yl] were supported on carbon materials (activated carbon, carbon xerogel and carbon nanotubes) and used for the oxidation of cyclohexane to cyclohexanol and cyclohexanone, with aqueous H2O2, under mild conditions.

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