4.6 Article

Zinc-catalyzed Meinwald rearrangement of tetrasubstituted 1-alkynyloxiranes to tertiary α-alkynylketones

Journal

CATALYSIS SCIENCE & TECHNOLOGY
Volume 3, Issue 4, Pages 932-934

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c2cy20810e

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Funding

  1. Ministerio de Economia y Competitividad of Spain (MINECO) [CQT-201020517-C02]

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Easy access to tertiary alpha-alkynylketones via a Meinwald-type rearrangement of 1-alkynyloxiranes is reported. This transformation is selectively accomplished with an economical zinc catalyst.

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