Journal
CATALYSIS SCIENCE & TECHNOLOGY
Volume 3, Issue 2, Pages 394-399Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c2cy20370g
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Funding
- Oak Ridge National Laboratory
- Scientific User Facilities Division, Office of Basic Energy Sciences, U.S. Department of Energy
- Fondazione Cariplo
- Empa
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The peculiar influence of a NiO support was studied by preparing gold catalysts supported on NiO1-x-TiO2 (x) mixed oxides. PVA protected Au nanoparticles showed high activity when supported on NiO for the selective oxidation of glycerol and ethane-1,2-diol. A detailed characterization of the resulting Au catalysts revealed a preferential deposition of the metal nanoparticles on the NiO phase. However, the activity of Au on NiO1-x-TiO2 (x) decreased with respect to pure NiO and the selectivity evolved with changes in the support.
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