Journal
CATALYSIS SCIENCE & TECHNOLOGY
Volume 1, Issue 1, Pages 58-61Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c0cy00055h
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- ERC
- EPSRC
- Spanish MICINN
- Royal Society
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Furans and pyrroles were prepared via the gold(I)-catalyzed alkyne hydration of diynes. The use of [Au(IPr)OH] as precatalyst in a silver-free protocol permits low catalyst loadings and in situ generation of the active cationic gold species. A detailed computational study confirmed the experimental results and supports the proposed mechanism.
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