4.6 Article

Miceller media accelerated Baylis-Hillman reaction

Journal

CATALYSIS SCIENCE & TECHNOLOGY
Volume 1, Issue 9, Pages 1641-1644

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c1cy00278c

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Triton X-100 aqueous micelle accelerates the rate of Baylis-Hillman reaction and enhances the product yield. The type and concentration of surfactants play prominent roles in the reaction. An aqueous micelle Triton X-100 is easily recovered and reused for four runs without substantial loss in yield. 1,4-diazabicyclo[2.2.2] octane (DABCO) (20 mol%) is found to be a good basic catalyst in aqueous micelle. Apparently, this protocol has several advantages such as green reaction medium, mild reaction condition, ease of product recovery and moderate-to-good yield of product.

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