4.6 Article

Green organophotocatalysis. TiO2-induced enantioselective α-oxyamination of aldehydes

Journal

CATALYSIS SCIENCE & TECHNOLOGY
Volume 1, Issue 6, Pages 923-926

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c1cy00183c

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Funding

  1. Korea Research Foundation [2010-0029617, 2010-0016079, 2010-0002396]
  2. National Research Foundation of Korea [2010-0002396] Funding Source: Korea Institute of Science & Technology Information (KISTI), National Science & Technology Information Service (NTIS)

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Asymmetric C-O bond formation with various aldehydes is examined under conditions of environmentally benign photo-organocatalysis. A heterogeneous TiO2 photocatalyst is used as a photooxidant in place of toxic and expensive chemical oxidants, for the first time in chemo- and stereoselective bond formation.

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