Journal
BEILSTEIN JOURNAL OF NANOTECHNOLOGY
Volume 3, Issue -, Pages 513-523Publisher
BEILSTEIN-INSTITUT
DOI: 10.3762/bjnano.3.59
Keywords
cathode; graphene; Li-ion battery; lithium manganate
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We report a facile method to prepare a nanoarchitectured lithium manganate/graphene (LMO/G) hybrid as a positive electrode for Li-ion batteries. The Mn2O3/graphene hybrid is synthesized by exfoliation of graphene sheets and deposition of Mn2O3 in a one-step electrochemical process, which is followed by lithiation in a molten salt reaction. There are several advantages of using the LMO/G as cathodes in Li-ion batteries: (1) the LMO/G electrode shows high specific capacities at high gravimetric current densities with excellent cycling stability, e. g., 84 mAh.g(-1) during the 500th cycle at a discharge current density of 5625 mA.g(-1) (similar to 38.01 C capacity rating) in the voltage window of 3-4.5 V; (2) the LMO/G hybrid can buffer the Jahn-Teller effect, which depicts excellent Li storage properties at high current densities within a wider voltage window of 2-4.5 V, e. g., 93 mAh.g(-1) during the 300th cycle at a discharge current density of 5625 mA.g(-1) (similar to 38.01 C). The wider operation voltage window can lead to increased theoretical capacity, e. g., 148 mAh.g(-1) between 3 and 4.5 V and 296 mAh.g(-1) between 2 and 4.5 V; (3) more importantly, it is found that the attachment of LMO onto graphene can help to reduce the dissolution of Mn2+ into the electrolyte, as indicated by the inductively coupled plasma (ICP) measurements, and which is mainly attributed to the large specific surface area of the graphene sheets.
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