Journal
ADVANCED ENERGY MATERIALS
Volume 8, Issue 29, Pages -Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/aenm.201801718
Keywords
lithium-ion batteries; nanoparticles; silicon-based composite anodes; solid electrolyte interfaces; surface oxide
Categories
Funding
- National Key Research and Development Program of China [2016YFB0901500, 2018YFB0905400]
- National Natural Science Foundation of China [21233004, 21473148, 21621091, 21761132030, 21703185]
- Fundamental Research Funds for the Central Universities (Xiamen University) [20720170042]
- US National Science Foundation [DMR-1410936]
- Division Of Materials Research [1410936] Funding Source: National Science Foundation
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Si/C composites represent one promising class of anode materials for next-generation lithium-ion batteries. To achieve high performances of Si-based anodes, it is critical to control the surface oxide of Si particles, so as to harness the chemomechanical confinement effect of surface oxide on the large volume changes of Si particles during lithiation/delithiation. Here a systematic study of Si@SiOx/C nanocomposite electrodes consisting of Si nanoparticles covered by a thin layer of surface oxide with a tunable thickness in the range of 1-10 nm is reported. It is shown that the oxidation temperature and time not only control the thickness of the surface oxide, but also change the structure and valence state of Si in the surface oxide. These factors can have a strong influence on the lithiation/delithiation behavior of Si nanoparticles, leading to different electrochemical performances. By combining experimental and modeling studies, an optimal thickness of about 5 nm for the surface oxide layer of Si nanoparticles is identified, which enables a combination of high capacity and long cycle stability of the Si@SiOx/C nanocomposite anodes. This work provides an in-depth understanding of the effects of surface oxide on the Si/C nanocomposite electrodes. Insights gained are important for the design of high-performance Si/C composite electrodes.
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