4.8 Article

High-Performance Planar-Heterojunction Solar Cells Based on Ternary Halide Large-Band-Gap Perovskites

Journal

ADVANCED ENERGY MATERIALS
Volume 5, Issue 1, Pages -

Publisher

WILEY-V C H VERLAG GMBH
DOI: 10.1002/aenm.201400960

Keywords

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Funding

  1. Air Force Office of Scientific Research [FA9550-09-1-0426]
  2. Office of Naval Research [N00014-11-1-0300]
  3. Asian Office of Aerospace RD [FA2386-11-1-4072]
  4. Boeing-Johnson Foundation
  5. NSF GRFP [DGE-1256082]

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High-performance planar-heterojunction (PHJ) solar cells based on large band-gap (1.70-1.83 eV) perovskites are demonstrated. By incorporating Cl- into the MAPb(I1-YBrY)3, the crystallinity and homogeneity of the solution-processed perovskite thin films are much improved, which results in an increased charge carrier diffusion length from approximate to 160 nm to approximate to 700-800 nm. This enhancement leads to a high power conversion efficiency (PCE) of 10% in the low-temperature solution-processed PHJ devices.

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