Journal
ADVANCED ENERGY MATERIALS
Volume 2, Issue 10, Pages 1232-1237Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/aenm.201200009
Keywords
charge-carrier recombination; charge-transfer states; electroluminescence; organic solar cells
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Funding
- Dutch Polymer Institute (DPI) [678]
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Charge-transfer (CT) state electroluminescence is investigated in several polymer:fullerene bulk heterojunction solar cells. The ideality factor of the electroluminescence reveals that the CT emission in polymer:fullerene solar cells originates from free-carrier bimolecular recombination at the donor-acceptor interface, rather than a charge-trap-mediated process. The fingerprint of the presence of nonradiative trap-assisted recombination, a voltage-dependent CT electroluminescence quantum efficiency, is only observed for the P3HT:PCBM system, which is explained by a reduction of the competing bimolecular recombination rate. These results are in agreement with measurements of the illumination-intensity dependence of the open-circuit voltage.
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