Journal
ADVANCED ENERGY MATERIALS
Volume 2, Issue 6, Pages 676-682Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/aenm.201100699
Keywords
block copolymers; dye-sensitized; mesoporous; self-assembly; solid state
Categories
Funding
- King Abdullah University of Science and Technology (KAUST) [KUS-C1-018-02]
- European Community under the SANS [246124]
- EPSRC [EP/F056702/1, EP/F065884/1]
- Department of Energy through the Cornell Fuel Cell Institute (CFCI) [DE-FG02 87ER45298]
- National Science Foundation [DMR-1104773]
- Cornell Fuel Cell Institute and the Energy Materials Center at Cornell (EMC2), an Energy Frontier Research Center
- US Department of Energy, Office of Science, Office of Basic Energy Sciences [DE-SC0001086]
- National 973 Program [2011CBA00702]
- Engineering and Physical Sciences Research Council [EP/F065884/1, EP/G049653/1, EP/F056702/1] Funding Source: researchfish
- EPSRC [EP/F056702/1, EP/F065884/1, EP/G049653/1] Funding Source: UKRI
- Direct For Mathematical & Physical Scien
- Division Of Materials Research [1104773] Funding Source: National Science Foundation
Ask authors/readers for more resources
A new self-assembly platform for the fast and straightforward synthesis of bicontinuous, mesoporous TiO2 films is presented, based on the triblock terpolymer poly(isoprene-b-styrene-b-ethylene oxide). This new materials route allows the co-assembly of the metal oxide as a fully interconnected minority phase, which results in a highly porous photoanode with strong advantages over the state-of-the-art nanoparticle-based photoanodes employed in solid-state dye-sensitized solar cells. Devices fabricated through this triblock terpolymer route exhibit a high availability of sub-bandgap states distributed in a narrow and low enough energy band, which maximizes photoinduced charge generation from a state-of-the-art organic dye, C220. As a consequence, the co-assembled mesoporous metal oxide system outperformed the conventional nanoparticle-based electrodes fabricated and tested under the same conditions, exhibiting solar power-conversion efficiencies of over 5%.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available