Journal
ADVANCED ENERGY MATERIALS
Volume 1, Issue 5, Pages 870-878Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/aenm.201100128
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Funding
- US Department of Energy Office of Basic Energy Science
- DOE
- Konarka Inc.
- Materials Research Science and Engineering Center
- Materials Science Facilities Network
- DOE, Office of Science, Office of Basic Energy Science
- Division Of Materials Research
- Direct For Mathematical & Physical Scien [820506] Funding Source: National Science Foundation
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Understanding the morphology of polymer-based bulk heterojunction (BHJ) solar cells is necessary to improve device efficiencies. Blends of a low-bandgap silole-containing conjugated polymer, poly[(4,4'-bis(2-ethylhexyl) dithieno[3,2-b;2',3'-d]silole)-2,6-diyl-alt-(4,7-bis(2-thienyl)-2,1,3-benzothiadiazole)-5,5'-diyl] (PSBTBT) with [6,6] phenyl-C61-butyric acid methyl ester (PCBM) were investigated under different processing conditions. The surface morphologies and vertical segregation of the As-Spun, Pre-Annealed, and Post-Annealed films were studied by scanning force microscopy, contact angle measurements, X-ray photoelectron spectroscopy, near-edge X-ray absorption fine structure spectroscopy, dynamic secondary ion mass spectrometry, and neutron reflectivity. The results showed that PSBTBT was enriched at the cathode interface in the As-Spun films and thermal annealing increased the segregation of PSBTBT to the free surface, while thermal annealing after deposition of the cathode increased the PCBM concentration at the cathode interface. Grazing-incidence X-ray diffraction and small-angle neutron scattering showed that the crystallization of PSBTBT and segregation of PCBM occurred during spin coating, and thermal annealing increased the ordering of PSBTBT and enhanced the segregation of the PCBM, forming domains similar to 10 nm in size, leading to an improvement in photo voltaic performance.
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