Journal
ACS CATALYSIS
Volume 8, Issue 9, Pages 8014-8019Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acscatal.8b02902
Keywords
deoxygenative hydrogenation; amide; manganese pincer complex; metal-ligand cooperation; amine
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Funding
- European Research Council (ERC) [AdG 692775]
- Sustainability and Energy Research Initiative (SAERI) foundation
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Deoxygenative hydrogenation of amides to amines homogeneously catalyzed by a complex of an Earth-abundant metal is presented. This manganese-catalyzed reaction features high efficiency and selectivity. A plausible reaction mechanism, involving metal-ligand cooperation of the manganese pincer complex, is proposed based on NMR studies and relevant stoichiometric reactions.
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