Journal
ACS CATALYSIS
Volume 4, Issue 6, Pages 1897-1900Publisher
AMER CHEMICAL SOC
DOI: 10.1021/cs5005129
Keywords
aerobic oxidation; visible light photoredox; indole formylation; Rose Bengal; transition-metal-free
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Funding
- NSFC [21102097]
- Scientific Research Foundation for the Returned Overseas Chinese Scholars, State Education Ministry
- Beijing National Laboratory for Molecular Sciences (BNLMS)
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An aerobic visible-light-promoted indole C-3 formylation reaction catalyzed by Rose Bengal has been developed. This transition-metal-free process employs molecular oxygen as the terminal oxidant and uses TMEDA as the one-carbon source through C-N bond cleavage. The reaction is compatible with a variety of functional groups.
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