Journal
ACS CATALYSIS
Volume 5, Issue 1, Pages 16-19Publisher
AMER CHEMICAL SOC
DOI: 10.1021/cs5015139
Keywords
low-temperature; solid-state ion-exchange; copper; zeolites; ammonia; nitric oxide
Categories
Funding
- Swedish Energy Agency [32900-1]
- Swedish Energy Agency
- AB Volvo
- ECAPS AB
- Haldor Topsoe A/S
- Scania CV AB
- Volvo Car Corporation AB
- Wartsila Finland Oy
- NordForsk
- Knut and Alice Wallenberg Foundation [KAW 2005.0055]
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The effect of the gas phase during solid-state ion-exchange of copper into zeolites was studied by exposing physical mixtures of copper oxides ((Cu2O)-O-I and (CuO)-O-II) and zeolites (MFI, *BEA, and CHA) to various combinations of NO, NH3, O-2, and H2O. It is shown that heating these mixtures to 250 degrees C results in active catalysts for the selective catalytic reduction of NO with NH3 (NH3-SCR), indicating that the Cu has become mobile at that temperature. Such treatment allows for a fast (<5-10 h) preparation of copper-exchanged zeolites. Scanning transmission electron microscopy analysis of Cu-CHA prepared using this method shows homogeneous distribution of the Cu in the primary particles of the zeolite. In situ XRD reveals that the Cu ion-exchange is related to the formation of (Cu2O)-O-I. When the zeolite is mixed with (CuO)-O-II, addition of NO to the NH3-containing gas phase enhances the formation of (Cu2O)-O-I and the Cu ion-exchange. The mobility of Cu at low temperatures is proposed to be related to the formation of [Cu-I(NH3)(x)](+) (x >= 2) complexes.
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