Journal
ACS CATALYSIS
Volume 4, Issue 11, Pages 4232-4241Publisher
AMER CHEMICAL SOC
DOI: 10.1021/cs501294j
Keywords
metathesis; surface chemistry; tungsten; tin; alkylation
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Funding
- CNRS
- French Ministry of Research and Higher Education
- Agence Nationale de la Recherche (OXOCAT) [ANR-12-BS07-0021-01]
- TGIR RMN THC [Fr3050]
- Agence Nationale de la Recherche (ANR) [ANR-12-BS07-0021] Funding Source: Agence Nationale de la Recherche (ANR)
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[WOCl4] was grafted on silica dehydroxylated at 200 degrees C, and the structure of the surface species was elucidated by a combination of spectroscopic and theoretical methods, demonstrating the formation of [( SiO)(2)WOCl2] (1a) as the major species accompanied by minor monopodal species [( SiO)WOCl3] (1b). Most noteworthy, EXAFS and O-17 NMR combined to DFT calculations helped elucidate the structure of the surface species. Alkylation was performed using SnMe4, affording methyl species that were also precisely characterized. The alkylated species achieved excellent performances in isobutene metathesis to 2,3-dimethylbutene.
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